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Issue 13, 1972
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Transition-metal tetra-oxo-complexes and their vibrational spectra

Abstract

The vibrational spectra of a number of transition metal tetra-oxo-complexes are reported for the first time, including those of salts containing the anions [RuO4]; [MO4]2–(M = Mn, Fe, or Ru); [MO4]3–(M = Cr, Mn, Re, or Fe); and [MO4]4–(M = Ti, V, Cr, Mo, W, Fe, or Co). From these measurements and published data on the fundamental frequencies of other such ions we calculate force constants for most of the known transition-metal tetra-oxoanions. Raman data on [Cr18O4]2– and [W18O4]2– are also presented

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J. Chem. Soc., Dalton Trans., 1972, 1416-1421
Article type
Paper

Transition-metal tetra-oxo-complexes and their vibrational spectra

F. Gonzalez-Vilchez and W. P. Griffith, J. Chem. Soc., Dalton Trans., 1972, 1416
DOI: 10.1039/DT9720001416

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