Nucleophilic aminations of 9-nitrophenanthrene and of 2-nitrobiphenylene have given 9-amino-10-nitrophenanthrene (I; R = NH2) and 2-amino-3-nitrobiphenylene (III; R = NH2) respectively; under the same conditions 1-nitrobiphenylene is unreactive. Some reactions of amines (I; R = NH2) and (III; R = NH2) are described.
J. W. Barton, A. R. Grinham and K. E. Whitaker, J. Chem. Soc. C, 1971, 1384 DOI: 10.1039/J39710001384
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