1H,2H-Octafluorocyclohexene, -hexafluorocyclopentene, and -tetrafluorocyclobutene have been treated with methanol in the presence of base, and the ethers formed fully characterised. Each reaction gave the ethers consistent with an addition–elimination mechanism and there was no evidence for direct allylic substitution.
A. B. Clayton, D. Collins, R. Stephens and J. C. Tatlow, J. Chem. Soc. C, 1971, 1177 DOI: 10.1039/J39710001177
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