Issue 0, 1971

The reaction of 3-hydroxy-2-naphthanilide with chloro-s-triazines

Abstract

N.m.r., i.r. data, and chemical behaviour support the view that ionised 3-hydroxy-2-naphthanilide reacts with cyanuric chloride and with dichloro-s-triazines to form initially the O-s-triazinyl derivatives (3). These hydrolyse in acid to 3-hydroxy-2-naphthanilide; in the presence of alkali, however, ON rearrangement of the s-triazine occurs to give the N-s-triazinyl derivatives (5) which hydrolyse to 3-hydroxy-2-naphthoic acid.

Article information

Article type
Paper

J. Chem. Soc. C, 1971, 1167-1170

The reaction of 3-hydroxy-2-naphthanilide with chloro-s-triazines

R. Budziarek and P. Hampson, J. Chem. Soc. C, 1971, 1167 DOI: 10.1039/J39710001167

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