The constitution and stereochemistry of a compound obtained by the acid-catalysed rearrangement of isophyllocladene epoxide have been confirmed by a synthesis of its enantiomer from (–)-neoatisirene. In addition, it has been shown that the neoatisiranol (XII) on dehydration undergoes skeletal rearrangement to the olefin (XIII).
P. A. Gunn, R. McCrindle and R. G. Roy, J. Chem. Soc. C, 1971, 1018 DOI: 10.1039/J39710001018
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