U.v. irradiation of the 16-oxo-oleanenes (1) and (2) yielded the γ-hydrogen transfer products, (4) and (5) respectively. Irradiation of cis-decalin-1,4-dione (3), a simple model for compounds (1) and (2), also gave a γ-hydrogen transfer product (6) in high yield. The irradiation of trans-decalin-1,4-dione was also studied.
N. Sugiyama, K. Yamada and H. Aoyama, J. Chem. Soc. C, 1971, 830 DOI: 10.1039/J39710000830
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