Issue 0, 1971

Chemistry of tropan-3-yl ethers. Part III. Kinetic properties of tropan-3α-yl methanesulphonate

Abstract

The reactions of tropan-3α-yl methanesulphonate with various nucleophiles have been investigated. Rate constants of the displacement reactions have been correlated with the configuration at C-3 of the reaction products. For stronger nucleophiles SN2 type reactions predominate over SNI type, and more β-substituted tropanes are produced than α-isomers.

Article information

Article type
Paper

J. Chem. Soc. B, 1971, 2154-2156

Chemistry of tropan-3-yl ethers. Part III. Kinetic properties of tropan-3α-yl methanesulphonate

P. Scheiber, G. Kraiss and K. Nádor, J. Chem. Soc. B, 1971, 2154 DOI: 10.1039/J29710002154

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