The mass spectral fragmentation of 1-methyl-4-phosphorinanone was found to follow two major pathways, each involving intial cleavage of a C–P bond. In addition, fragments were detected which resulted from transfer of oxygen to phosphorus. The pattern was quite different from that of N-methyl-4-piperidone, the spectrum of which resembled that of N-methylpiperidine, with initial cleavage occurring at the 2,3-bond.
L. D. Quin and T. P. Toube, J. Chem. Soc. B, 1971, 832 DOI: 10.1039/J29710000832
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