The apparent dipole moments and molar Kerr constants found for Ac2O and Ac2S as solutes in carbon tetrachloride or benzene are reconcilable with non-planar conformations derivable from the s-cis models by rotating each acetyl group within the range 130–140° in a clockwise sense (looking from the central atom towards Ac).
P. A. Hopkins and R. J. W. Le Fèvre, J. Chem. Soc. B, 1971, 338 DOI: 10.1039/J29710000338
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