Condensation of 1,3-hexasulphur di-imide with chlorosulphanes as a route to fused-ring sulphur nitrides
Abstract
The condensations of 1,3-hexasulphur di-imide with dichloropenta-, tri-, and hepta-sulphanes have been investigated with the aim of preparing fused-ring sulphur nitrides. The known fused-ring compound S11N2 resulted from all three chlorosulphanes, dichloropentasulphane giving yields as high as 38%. The new compounds sought, S9N2 and S13N2, could not be made.