SCHEDULED MAINTENANCE:
The reaction of di-iron enneacarbonyl with aminofluorophosphines results in the formation of compounds of the type R2NPF2Fe(CO)4 or (R2N)2PF,FeCO4, and Fe(CO)5. The aminofluorophosphineiron tetracarbonyl derivatives react with anhydrous HCl and HBr to form mixed halogenophosphine adducts containing the Fe(CO)4 moiety. The reaction of Fe(CO)4,PF2Br with various salts is discussed.
W. M. Douglas and J. K. Ruff, J. Chem. Soc. A, 1971, 3558 DOI: 10.1039/J19710003558
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