Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Studies on the temperature dependence in the 1H n.m.r. spectra of some methylcyclopentadienyl metal compounds

C. H. Campbell  and  M. L. H. Green  

Abstract

The temperature dependence (+20 to –95°) of the 1H n.m.r. spectra of the compounds Sn(MeC5H4)4 and Hg(MeC5H4)2 has been determined and the data is interpreted in terms of rapidly exchanging fluxional σ-bonded systems. The spectra (+20 to –95°) of the compounds Au(PPh3)(RC5H4)(R = H or Me) in 2-methyltetrahydrofuran are also consistent with there being fluxional σ-bonded RC5H4 rings.

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Article information

DOI
https://doi.org/10.1039/J19710003282
Article type
Paper

J. Chem. Soc. A, 1971, 3282-3285

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Studies on the temperature dependence in the 1H n.m.r. spectra of some methylcyclopentadienyl metal compounds

C. H. Campbell and M. L. H. Green, J. Chem. Soc. A, 1971, 3282 DOI: 10.1039/J19710003282

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