The 35Cl n.q.r. frequencies at 77 K of two chloro(phenyl)phosphoranes, four cyclic phosphorus esters, four phosphoryl and thiophosphoryl chlorides, and eight chlorophosphates, are reported. The frequencies are used to predict possible molecular structures, and are related to σ- and π-bond effects within the molecules, by use of BEEM.
R. M. Hart and M. A. Whitehead, J. Chem. Soc. A, 1971, 1738 DOI: 10.1039/J19710001738
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