The magnetic parameters of PO2F– in potassium difluorophosphate show that this pyramidal radical is structurally similar to the isoelectronic radical PO32–, the spin-density on phosphorus being slightly increased and the p:s ratio on phosphorus slightly reduced. The isotropic coupling to 19F (165 G) is similar to that for CF3.
A. Begum, S. Subramanian and M. C. R. Symons, J. Chem. Soc. A, 1971, 700 DOI: 10.1039/J19710000700
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