New complexes of palladium(II) containing as ligands R-azo-cyclohexene derivatives have been prepared. Their characterisation by way of various physical-chemical techniques, including 1H n.m.r. and i.r. spectra, indicate that they are all neutral complexes of the type trans-PdL2Cl2 and that the co-ordination occurs through a nitrogen–palladium σ-bond.
Some aspects of their chemical properties are also reported and discussed.
L. Caglioti, L. Cattalini, F. Gasparrini, G. Marangoni and P. A. Vigato, J. Chem. Soc. A, 1971, 324 DOI: 10.1039/J19710000324
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