The extended conjugated system of epoxylathyrol can be quantitatively isomerised by light to the cis, non-planar, enone (7), and thence to the fragmentation product (3), a furan.
A. Balmain and G. Ourisson, J. Chem. Soc. D, 1971, 268b DOI: 10.1039/C2971000268B
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