A model for non-head to tail monoterpene biosynthesis involving conversion of the artemisyl skeleton into the chrysanthemyl skeleton is proposed and supported by the solvolytic conversion of an artemisyl sulphonium salt into a chrysanthemic derivative; the relationship to squalene biogenesis is discussed.
B. M. Trost, P. Conway and J. Stanton, J. Chem. Soc. D, 1971, 1639 DOI: 10.1039/C29710001639
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