In the rearrangement of 2-oxopropane-1,2-dioxy diradicals, generated via thermolysis of β-peroxylactones, an asymmetric alkyl substitutent is shown to migrate with quantitative retention of configuration.
W. Adam and C. Wilkerson, J. Chem. Soc. D, 1971, 1569 DOI: 10.1039/C29710001569
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