Bromotrichloromethane undergoes a photochemically induced reaction with triethylborane and related trialkylboranes to produce chloroform and the corresponding α-bromotrialkylborane; the reaction provides a method for producing the reactive α-bromo-organoborane without the simultaneous production of destructive hydrogen bromide.
H. C. Brown and Y. Yamamoto, J. Chem. Soc. D, 1971, 1535 DOI: 10.1039/C29710001535
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