Hydrogen bromide is shown to have a pronounced effect on atomic brominations in the gas phase; this is due to two effects, (i) a possible reversible reaction of alkyl radicals with hydrogen bromide, and (ii) the direct reaction between hydrogen bromide and alkyl bromides leading to olefins.
D. S. Ashton, J. M. Tedder and J. C. Walton, J. Chem. Soc. D, 1971, 1487 DOI: 10.1039/C29710001487
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