Low-valent phosphine–platinum complexes react with Fe2(CO)9, Ru3(CO)12, or H2Os(CO)4 to give heteronuclear cluster compounds of the types Fe2Pt(CO)10-nLn(n= 1 or 2), MPt2(CO)5L3, and M2Pt(CO)7L3(M = Ru, Os); the ligand L may be any one of a variety of substituted phosphines or phosphites, or triphenylarsine.
M. I. Bruce, G. Shaw and F. G. A. Stone, J. Chem. Soc. D, 1971, 1288 DOI: 10.1039/C29710001288
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