The variation in reactivity of cyclo-octa-1,5-diene and cyclo-octa-1,3,5-triene complexes of d8 metals is considered with particular to protonation of the cyclopentadienylrhodium(I) derivatives; the systems show a remarkable facility for prototopic rearrangements producing a variety of organic isomers.
J. Evans, B. F. G. Johnson and J. Lewis, J. Chem. Soc. D, 1971, 1252 DOI: 10.1039/C29710001252
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