Issue 20, 1971

Absolute configuration of the C18 juvenile hormone: application of a new circular dichroism method using tris(dipivaloylmethanato)praseodymium

Abstract

The absolute configuration of the C18 juvenile hormone has been established as being (10R : 11S)-(I); this is based on clarification of the mode of epoxide cleavage, and a determination of the chirality of the resultant α-glycol by a new c.d. method employing Pr(dpm)3.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1235-1236

Absolute configuration of the C18 juvenile hormone: application of a new circular dichroism method using tris(dipivaloylmethanato)praseodymium

K. Nakanishi, D. A. Schooley, M. Koreeda and J. Dillon, J. Chem. Soc. D, 1971, 1235 DOI: 10.1039/C29710001235

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