Study of the 1H n.m.r. spectra of the N-acyl-prolines (I) and (II) in deuteriochloroform over a range of temperature has enabled the thermodynamic parameters for the interconversion of such conformers by rotation about the N–CO bond to be evaluated for the first time.
H. L. Maia, K. G. Orrell and H. N. Rydon, J. Chem. Soc. D, 1971, 1209 DOI: 10.1039/C29710001209
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