Photo-irradiation of 3-allyloxy- and 3-allylamino-cyclohex-2-enones results in an intramolecular cyclo-addition to produce oxa- and aza-bicyclo[2,1,1]hexane derivatives.
Y. Tamura, Y. Kita, H. Ishibashi and M. Ikeda, J. Chem. Soc. D, 1971, 1167 DOI: 10.1039/C29710001167
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