Issue 17, 1971

Hexafluoroacetone adducts of 1-phenylphosphetans. The barrier to placing a four-membered ring diequatorial in a trigonal bipyramid : nuclear magnetic resonance study

Abstract

The variable temperature 19F n.m.r. spectrum of the 1 : 2-adduct of 2,2,4,4-tetramethyl-1-phenylphosphetan and hexafluoroacetone leads to a free energy of activation for placing the phosphetan ring diequatorial of 20·1 kcal mol–1.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1011-1012

Hexafluoroacetone adducts of 1-phenylphosphetans. The barrier to placing a four-membered ring diequatorial in a trigonal bipyramid : nuclear magnetic resonance study

R. E. Duff, R. K. Oram and S. Trippett, J. Chem. Soc. D, 1971, 1011 DOI: 10.1039/C29710001011

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