Thermal rearrangement of the optically active (ethylmethylphenyl)methyl isocyanide R(+)-(I) gave three elimination products (IV)–(VI) together with almost racemic cyanide (III)via a novel radical mechanism.
S. Yamada, M. Shibasaki and S. Terashima, J. Chem. Soc. D, 1971, 1008 DOI: 10.1039/C29710001008
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