Issue 16, 1971
From the journal:

Journal of the Chemical Society D: Chemical Communications

Cyclopentadienyldicarbonyliron derivatives of arsenic, antimony and bismuth with M–Fe σ-bonds (M[double bond, length as m-dash]As, Sb, Bi)

W. R. Cullen,   D. J. Patmore,   J. R. Sams,   M. J. Newlands  and  L. K. Thompson  

Abstract

The reactions of MX3(M = As, Sb; X = Cl, Br) with [Fe(CO)2(π-C5H5)]2 in CH2Cl2 solution give ionic derivatives containing the [X2M{Fe(CO)2(π-C5H5)}2]+ cation as well as the neutral compounds X2AsFe(CO)2(π-C5H5), while similar reactions of SbX3 and BiX3(X = Cl, Br, I) in C6H6 or tetrahydrofuran yield X2MFe(CO)2(π-C5H5) and XSb[Fe(CO)2(π-C5H5)]2.

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Article information

DOI
https://doi.org/10.1039/C29710000952
Article type
Paper

J. Chem. Soc. D, 1971, 952-953

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Cyclopentadienyldicarbonyliron derivatives of arsenic, antimony and bismuth with M–Fe σ-bonds (M[double bond, length as m-dash]As, Sb, Bi)

W. R. Cullen, D. J. Patmore, J. R. Sams, M. J. Newlands and L. K. Thompson, J. Chem. Soc. D, 1971, 952 DOI: 10.1039/C29710000952

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