t-Butoxy radicals generated by photolysis of di-t-butyl peroxide, or thermolysis of di-t-butyl hyponitrite, are quantitatively reduced to t-butoxide ion by electron transfer from paraquat cation radical; the reaction affords a novel and convenient method of studying rates of homolytic fission in organic molecules.
A. S. Hopkins and A. Ledwith, J. Chem. Soc. D, 1971, 830 DOI: 10.1039/C29710000830
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