Alkyl-lithium reagents add to unstrained unconjugated C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C double bonds if the alkene contains a dimethylamino-group or a thio-either group in such a position, that intramolecular complexation of the new alkyl-lithium formed is possible.
A. H. Veefkind, J. v. d. Schaaf, F. Bickelhaupt and G. W. Klumpp, J. Chem. Soc. D, 1971, 722 DOI: 10.1039/C29710000722
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