The preferred stereospecific and regiospecific path for the addition of typical electrophilic reagents to the 22(23)-ethylenic linkage of the ergosterol side-chain has been establised.
D. H. R. Barton, J. P. Poyser, P. G. Sammes, M. B. Hursthouse and S. Neidle, J. Chem. Soc. D, 1971, 715 DOI: 10.1039/C29710000715
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