The rate of molecular rearrangement of bis-(phenoxy)bis(chelate)titanium(IV) complexes increases with decreasing PKa of the parent phenol and the activation entropies for the rearrangement are large and negative.
J. F. Harrod and K. Taylor, J. Chem. Soc. D, 1971, 696 DOI: 10.1039/C29710000696
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