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Electrolytic oxidation of armepavine and N-norarmepavine leads to fragmentation, but the oxidation of N-carbethoxy-N-norarmepavine yields carbon–carbon dimers and, for the first time, the carbon–oxygen dimer akeleton of the alkaloid, dauricine.
J. M. Bobbitt and R. C. Hallcher, J. Chem. Soc. D, 1971, 543 DOI: 10.1039/C29710000543
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