Uncatalysed alcoholysis of alkyl acetoacetates and malonates occurs via a unimolecular dissociative mechanism involving concerted elimination of alcohol with resultant formation of substituted ketens as reactive intermediates.
D. S. Campbell and C. W. Lawrie, J. Chem. Soc. D, 1971, 355 DOI: 10.1039/C29710000355
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