Issue 7, 1971

X-Ray crystallographic determination of the molecular structure of B9C2H12AlMe2, a non-rigid aluminio-carborane derivative

Abstract

Determination of the molecular structure of B9C2H12AlMe2 by single-crystal X-ray diffraction techniques, shows that the aluminium atom is involved in bonding only to two boron atoms of the B9C2H12 icosahedral fragment: 11B n.m.r. studies suggest that, in solution, the molecule undergoes rapid intramolecular rearrangements.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 298-299

X-Ray crystallographic determination of the molecular structure of B9C2H12AlMe2, a non-rigid aluminio-carborane derivative

M. R. Churchill, A. H. Reis, D. A. T. Young, G. R. Willey and M. F. Hawthorne, J. Chem. Soc. D, 1971, 298 DOI: 10.1039/C29710000298

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