The laser Raman spectra of π-allylpalladium chloride and its complexes with triphenylphosphine and dimethyl sulphoxide show that the co-ordination of these ligands with the Pd atom in π-allylpalladium complexes does not cause the conversion of the π-allyl group to the asymmetric of σ-bonded form, but that only a cleavage of the bridged Pd–Cl bond occurs.
L. A. Leites, V. T. Aleksanyan, S. S. Bukalov and A. Z. Rubezhov, J. Chem. Soc. D, 1971, 265 DOI: 10.1039/C29710000265
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