5-Substituted 4-oxahomoadamantanes are formed in the reaction of 2-substituted adamantan-2-ols with lead tetra-acetate and iodine; novel routes to 1-substituted 2-oxa-adamantanes are reported, and the mechanisms of these reactions are discussed.
R. M. Black and G. B. Gill, J. Chem. Soc. D, 1971, 172 DOI: 10.1039/C29710000172
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