In contradistinction to a recent report that the free-radical addition of menthyl methylphosphinate to alkenes proceeds with inversion of configuration at phosphorus, dibenzoyl peroxide-catalysed addition of menthyl phenylphosphinate to cyclohexene occurs with retention of configuration.
W. B. Farnham, R. K. Murray and K. Mislow, J. Chem. Soc. D, 1971, 146 DOI: 10.1039/C29710000146
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