Crystal of tris(trimethylphosphine sulphide)-copper(I) perchlorate have been shown by X-ray diffraction to contain monomeric, trigonally co-ordinated cations, the free ligand being little changed in geometry upon co-ordination.
P. G. Eller and P. W. R. Corfield, J. Chem. Soc. D, 1971, 105 DOI: 10.1039/C29710000105
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