Reaction of aliphatic alk-1-ynes with IrH(CO)(PPh3)3 or IrH(CO)2(PPh3)2 results in loss of hydrogen and formation of novel acetylides Ir(C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CR)(CO)(PPh3)2 or 3: the square bistriphenylphosphine species undergo a wide range of oxidative-addition reactions.
C. K. Brown and G. Wilkinson, J. Chem. Soc. D, 1971, 70 DOI: 10.1039/C29710000070
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