Direct and sensitized photodecomposition of exo- and endo-2-methyl-3,4-diazabicyclo[3,3,0]oct-3-enes proceeds through singlet and triplet diradical intermediates, but predominant single inversion of configuration in the products formed on thermal decomposition indicates a more complex mechanism.
P. B. Condit and R. G. Bergman, J. Chem. Soc. D, 1971, 4b DOI: 10.1039/C2971000004B
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