2,4-Diaxial-dibromoadamantane (V) and 2,4-diaxial-dihydroxyadamantane (VII) are obtained by bromination of protoadamantene (I) and by treatment of protoadamantene epoxide (VI) with aqueous acid, respectively.
D. Lenoir, P. von Ragué Schleyer, C. A. Cupas and W. E. Heyd, J. Chem. Soc. D, 1971, 26 DOI: 10.1039/C29710000026
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