SCHEDULED MAINTENANCE
The dipole moments of cis- and trans-4-p-nitrophenylcyclohexylamine are used to deduce the rotamer populations of an axial amine group in the cyclohexane system as 66% with lone pair ‘in’ and 34% with lone pair ‘out’, corresponding to ΔG°= 0·70 kcal./mole.
M. J. Cook, R. A. Y. Jones, A. R. Katritzky, D. G. Markees, A. C. Richards and L. G. Jacks, J. Chem. Soc. B, 1971, 1327 DOI: 10.1039/J29710001327
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