Issue 0, 1971

Nuclear magnetic resonance study of dipolar contribution to the ground state in a series of fulvenes

Abstract

A series of fulvenes derived from isodicyclopentadiene has been prepared and their n.m.r. spectra studied. The simple low-field spectrum enabled immediate assignment of Hα and both Hγ-cis. and Hγ-trans. The shifts are correlated with π-electron densities calculated for a model compound and the transmission of charge from the α-carbon to the five-membered ring was found to be between that for styrenes and trans-cinnamic acids.

Article information

Article type
Paper

J. Chem. Soc. B, 1971, 385-388

Nuclear magnetic resonance study of dipolar contribution to the ground state in a series of fulvenes

A. Pines and M. Rabinovitz, J. Chem. Soc. B, 1971, 385 DOI: 10.1039/J29710000385

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