Issue 19, 1971

Evidence for cis- and trans-1,2,3-triphenylaziridine from the ring-opened azomethine ylides

Abstract

cis-1,2,3-Triphenylaziridine equilibrates at 150° with the trans-isomer until a 78 : 22 mixture is attained.; the configurational assignments are based on the conrotatory ring-openings to azomethine ylides which were intercepted by suitable dipolarophiles.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1188-1190

Evidence for cis- and trans-1,2,3-triphenylaziridine from the ring-opened azomethine ylides

J. H. Hall, R. Huisgen, C. H. Ross and W. Scheer, J. Chem. Soc. D, 1971, 1188 DOI: 10.1039/C29710001188

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