The oxidation of oxalic acid by thallium(III) in 3 M (Na++ H+) perchlorate solutions can be described by the following scheme : Tl3++ H2C2O4⇌ TlC2O+4+ 2H+(K25°= 8.6 × 102 mol l.–1, ΔHo=–3.4 kcal mol–1) followed by TlC2O+4→ Tl++2 CO2(k= 1016.2 exp (–28.400/RT) s–1).
L. B. Mønsted, O. Mønsted and G. Nord (Waind), Trans. Faraday Soc., 1970, 66, 936 DOI: 10.1039/TF9706600936
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