Reflection i.-r. absorption spectra of CO adsorbed on thick film copper mirrors at room temperature show a narrow band at 2105 cm–1 accompanied by a broad band at 2092 cm–1. The relative intensities of these bands are variable for films deposited in ultra-high vacuum conditions. The dependences of absorption on angle of incidence and plane of polarization are in qualitative agreement with the theoretical predictions of Greenler.
J. Pritchard and M. L. Sims, Trans. Faraday Soc., 1970, 66, 427 DOI: 10.1039/TF9706600427
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