The rearrangement of N-(α-substituted benzyl)-NN-dimethylanilinium hydroxides (I) to give the ortho- and para-substituted NN-dimethylanilines (II) and (III) has been studied. Radical intermediates are proposed for the intramolecular reaction.
D. A. Archer, H. Booth and R. D. Stangroom, J. Chem. Soc. C, 1970, 2276 DOI: 10.1039/J39700002276
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