The configuration of homoproaporphine at the spiro-centre is deduced from c.d. data for the derivatives (VII) and (X). An enol-ether addition reaction and a dienone-phenol rearrangement of the homoproaporphine (IX) are described. Dienol–benzene rearrangements of dienols (XIIIa) and (XIIIb) are also described.
T. Kametani, F. Satoh, H. Yagi and K. Fukumoto, J. Chem. Soc. C, 1970, 382 DOI: 10.1039/J39700000382
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