The 1-methyl site of alkyl substituted 5-aminotetrazoles was found to be the most susceptible to γ-irradiation. The main paramagnetic radicals formed were identified as CH3· and R–CH2·(R = substittuted 5-aminotetrazole). With a 5-nitraminotetrazole claeavage of the nitramino N–N bond, yielding an NO2· radical, was the major interaction.
R. N. Butler, R. C. Catton and M. C. R. Symons, J. Chem. Soc. B, 1970, 378 DOI: 10.1039/J29700000378
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